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Organic Chemistry Essay Example

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Organic Chemistry

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This reduction will yield an E-alkene. Using Lindlars catalyst, Z-alkene can be produce. An imine reacts with dienes in the Aza Diels-Alder reaction to produce tetrahydropyridine. In Hoesch reaction , a type of Friedel-Crafts Acylation reaction, imine is reacted with a nitrile, hydrochloric acid and an arene to form an aryl ketone. In direct addition of TMS-acetylene to Aldimines, the absence of polar solvent is desirable to prevent any attack to nitrogen and Propargyl group that can jeopardize the synthesis.Alberto Otero, María-José [ONLINE] Available at: 

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References

Jerry March, 1986. Advanced Organic Chemistry. 3rd Edition. John Wiley & Sons Inc.

Li-Xin Dai, Ying-Rui Lin, Xue-Long Hou and Yong-Gui Zhou, 2000. Stereoselective Reactions with Imines. ChemInform Abstract: Stereoselective Reactions with Imines, 31(5).

Alberto Otero, María-José Chapela, Miroslava Atanassova, Juan M. Vieites, and Ana G. Cabado (2011). Cyclic Imines: Chemistry and Mechanism of Action: A Review - Chemical Research in Toxicology (ACS Publications) . 2011. Cyclic Imines: Chemistry and Mechanism of Action: A Review - Chemical Research in Toxicology (ACS Publications) . [ONLINE] Available at: <http://pubs.acs.org/doi/abs/10.1021/tx200182m>. [Accessed 3 December 2011].

El Hajjaji, Samir,  2010. Asymmetric transition metal-catalyzed alkyl addition to imines with chiral phosphine ligands - Nottingham eTheses. 2011. Asymmetric transition metal-catalyzed alkyl addition to imines with chiral phosphine ligands - Nottingham eTheses. [ONLINE] Available at: <http://etheses.nottingham.ac.uk/1185/>. [Accessed 4 December 2011].

Mehta, Akul. Imines and Enamines - Nitrogen Analogs of Enols and Enolates | Notes | PharmaXChange.info. 2011. Imines and Enamines - Nitrogen Analogs of Enols and Enolates | Notes | PharmaXChange.info. [ONLINE] Available at: <http://pharmaxchange.info/press/2011/04/imines-and-enamines-nitrogen-analogs-of-enols-and-enolates/.> [Accessed 5 December 2011].

Tolbert, T. L. and Bruce Houston.  The Preparation of Aldimines through the Stephen Reaction1 - The Journal of Organic Chemistry (ACS Publications) . 2011. The Preparation of Aldimines through the Stephen Reaction1 - The Journal of Organic Chemistry (ACS Publications) . [ONLINE] Available at: <http://pubs.acs.org/doi/abs/10.1021/jo01038a022>. [Accessed 4 December 2011].

Barluenga, José Prof., Fernando Aznar Dr. and Dr., Carlos Valdés, 2004. N-Trialkylsilylimines as Coupling Partners for Pd-Catalyzed CN Bond-Forming Reactions: One-Step Synthesis of Imines and Azadienes from Aryl and Alkenyl Bromides. Angewandte Chemie, 116(3), pp.347-349.

Ibrahim, Mohamed N. and Hazem K Al-Deeb, 2006. Synthesis, Characterization and Study of the Biological activity of Some Aldimines Derivatives. E-Journal of Chemistry, 3(4), pp.257-261.

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